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- W2157070382 abstract "Abstract By fine-tuning the substituents on the nitrogen of (1 S ,2 R ) and (1 R ,2 S )-1,2-diphenyl-2-aminoethanols, a chiral ligand 2b was obtained, which showed excellent enantioselectivity, with up to 94% e.e, for the asymmetric addition of diethylzinc to N -diphenylphosphinoylimines 1 . In one example, the optically active amide 3c was converted into a new amine 5 with 98% e.e. by a reaction sequence involving Suzuki coupling and hydrolysis without racemization." @default.
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- W2157070382 date "2010-05-23" @default.
- W2157070382 modified "2023-09-27" @default.
- W2157070382 title "ChemInform Abstract: Enantioselective Addition of Diethylzinc to N-Diphenylphosphinoylimines Employing N,N-Dialkyl-1,2-diphenyl-2-aminoethanols as Chiral Ligands." @default.
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- W2157070382 doi "https://doi.org/10.1002/chin.200146167" @default.
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