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- W2157150209 abstract "ip = 5-hydroxyisophthalic acid), which were fully characterized by elemental analysis, IR spectroscopy, single crystalX-ray crystallography, thermogravimertric analysis and luminescence spectra. Structure determinationrevealed that one-dimensional (1-D) polymeric chains for 1 and 3, and 2-D layered structure for 2 aresignificantly directed by the coordination mode of the carboxylate groups from aromatic coligands. In contrast,the terminal hptrz ligand affords its uncoordinated phenolic OH group to form classical H-bond interactionswith coordinated water and/or carboxylate groups, which are responsible for the formation of 3-Dsupramolecular networks. In addition, the three solid coordination polymers with considerable thermal stabilitypresent strong hptrz-based fluorescence emissions at room temperature.Key Words : 1-(4-Hydroxyphenyl)-1H-1,2,4-triazole, Mixed-ligand, Coordination polymerIntroductionDuring the past decades, 1,2,4-triazole (Htrz) and itsdiverse derivatives have already becoming one of the mostpromising ligands, and are widely applied upon the con-struction of various transitional metal complexes with lumine-scence, magnetic and ion precursor properties." @default.
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- W2157150209 date "2008-11-20" @default.
- W2157150209 modified "2023-09-24" @default.
- W2157150209 title "Three 1-(4-Hydroxyphenyl)-1H-1,2,4-triazole-based Cd(II) Coordination Polymers Directed by Aromatic Polycarboxylate Coligands" @default.
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- W2157150209 doi "https://doi.org/10.5012/bkcs.2008.29.11.2195" @default.
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