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- W2157284053 abstract "Laser flash photolysis experiments have shown that the diquat analog containing a propylene bridge (PDQ2+), when electrostatically bound to negatively-charged vesicles containing chlorophyll, is able to mediate the rapid reduction (k= 1.1 × 105 s-1) of spinach ferredoxin via electron transfer quenching of triplet state chlorophyll. The kinetics of formation and decay of reduced ferredoxin are consistent with a mechanism involving complex formation between oxidized ferredoxin and vesicle-bound PDQ2+. Under optimal conditions, approximately 15% of the quenched triplets yield reduced ferredoxin. This process is a model for soluble ferredoxin reduction which occurs in green plant photosystem I, and results in an appreciable storage of electromagnetic energy in the reaction products." @default.
- W2157284053 created "2016-06-24" @default.
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- W2157284053 date "1989-03-01" @default.
- W2157284053 modified "2023-09-25" @default.
- W2157284053 title "SPINACH FERREDOXIN REDUCTION BY MEMBRANE-BOUND CHLOROPHYLL TRIPLET STATE VIA A DIQUAT MEDIATOR" @default.
- W2157284053 doi "https://doi.org/10.1111/j.1751-1097.1989.tb04117.x" @default.
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