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- W2157313159 abstract "Abstract The first enantioselective copper‐catalyzed decarboxylative propargylic alkylation has been developed. Treatment of propargyl β‐ketoesters with a catalyst, prepared in situ from [Cu(CH 3 CN) 4 BF 4 ] and a newly developed chiral tridentate ketimine P,N,N‐ligand under mild reaction conditions, generates β‐ethynyl ketones in good yields and with high enantioselectivities without requiring the pregeneration of ketone enolates. This new process provides facile access to a range of chiral β‐ethynyl ketones in a highly enantioenriched form." @default.
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- W2157313159 date "2013-12-18" @default.
- W2157313159 modified "2023-10-18" @default.
- W2157313159 title "Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargyl β-Ketoesters with a Chiral Ketimine P,N,N-Ligand" @default.
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- W2157313159 doi "https://doi.org/10.1002/anie.201309182" @default.
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