Matches in SemOpenAlex for { <https://semopenalex.org/work/W2157409402> ?p ?o ?g. }
- W2157409402 endingPage "61" @default.
- W2157409402 startingPage "53" @default.
- W2157409402 abstract "New cyclometalated platinum(II) complexes [PtMe(C^N)L], 1, in which C^N = deprotonated 2-phenylpyridine (ppy), benzo[h]quinoline (bhq) or 2-(p-tolyl)pyridine (tpy) and L = PPh3 or PMePh2, were synthesized by the reaction of [PtMe(C^N)(SMe2)] with 1 equiv of L. The reaction of complexes 1 with MeI gave the cyclometalated Pt(IV) complexes [PtMe2I(C^N)L], 3. On the basis of kinetic studies, using Uv–visible spectroscopy, it was suggested that the latter oxidative addition reactions were proceeded by an SN2 mechanism. The rates of the reactions at different temperatures were measured and consistent with the proposed mechanism, large negative ΔS‡ values were found for each reaction. Besides, rate of reactions (in CHCl3) involving the PPh3 complexes [PtMe(C^N)(PPh3)], were almost 3–5 times slower than those involving the PMePh2 complexes [PtMe(C^N)(PMePh2)]. This was attributed to the electronic and steric effects of PPh3 ligand as compared with that of PMePh2 ligand which was further confirmed using density functional theory (DFT) calculations through finding approximate structures for the described complexes." @default.
- W2157409402 created "2016-06-24" @default.
- W2157409402 creator A5001288879 @default.
- W2157409402 creator A5008205291 @default.
- W2157409402 creator A5035727683 @default.
- W2157409402 creator A5045013701 @default.
- W2157409402 creator A5046393755 @default.
- W2157409402 creator A5051719308 @default.
- W2157409402 creator A5066738952 @default.
- W2157409402 date "2012-02-01" @default.
- W2157409402 modified "2023-10-16" @default.
- W2157409402 title "Oxidative addition of MeI to some cyclometalated organoplatinum(II) complexes: Kinetics and mechanism" @default.
- W2157409402 cites W1565971350 @default.
- W2157409402 cites W1968456335 @default.
- W2157409402 cites W1971425837 @default.
- W2157409402 cites W1971716348 @default.
- W2157409402 cites W1973441858 @default.
- W2157409402 cites W1978580385 @default.
- W2157409402 cites W1979839175 @default.
- W2157409402 cites W1982272281 @default.
- W2157409402 cites W1984614201 @default.
- W2157409402 cites W1990514145 @default.
- W2157409402 cites W2000546310 @default.
- W2157409402 cites W2003614650 @default.
- W2157409402 cites W2005661768 @default.
- W2157409402 cites W2008369175 @default.
- W2157409402 cites W2009874493 @default.
- W2157409402 cites W2015554875 @default.
- W2157409402 cites W2016410175 @default.
- W2157409402 cites W2017732168 @default.
- W2157409402 cites W2021231925 @default.
- W2157409402 cites W2022573775 @default.
- W2157409402 cites W2023271753 @default.
- W2157409402 cites W2024073731 @default.
- W2157409402 cites W2029666347 @default.
- W2157409402 cites W2032458896 @default.
- W2157409402 cites W2032647209 @default.
- W2157409402 cites W2034150875 @default.
- W2157409402 cites W2036241142 @default.
- W2157409402 cites W2036512185 @default.
- W2157409402 cites W2040299058 @default.
- W2157409402 cites W2043755772 @default.
- W2157409402 cites W2044471715 @default.
- W2157409402 cites W2044490585 @default.
- W2157409402 cites W2046627791 @default.
- W2157409402 cites W2048057335 @default.
- W2157409402 cites W2049460180 @default.
- W2157409402 cites W2060426814 @default.
- W2157409402 cites W2062077700 @default.
- W2157409402 cites W2068617439 @default.
- W2157409402 cites W2073881756 @default.
- W2157409402 cites W2075936357 @default.
- W2157409402 cites W2078402159 @default.
- W2157409402 cites W2084853411 @default.
- W2157409402 cites W2087568627 @default.
- W2157409402 cites W2087847947 @default.
- W2157409402 cites W2088180815 @default.
- W2157409402 cites W2089418193 @default.
- W2157409402 cites W2089774218 @default.
- W2157409402 cites W2092039030 @default.
- W2157409402 cites W2092511375 @default.
- W2157409402 cites W2094392858 @default.
- W2157409402 cites W2095539061 @default.
- W2157409402 cites W2100500546 @default.
- W2157409402 cites W2101584728 @default.
- W2157409402 cites W2105236781 @default.
- W2157409402 cites W2111225834 @default.
- W2157409402 cites W2114791757 @default.
- W2157409402 cites W2121832045 @default.
- W2157409402 cites W2135249528 @default.
- W2157409402 cites W2143981217 @default.
- W2157409402 cites W2162333984 @default.
- W2157409402 cites W2170299075 @default.
- W2157409402 cites W2319930853 @default.
- W2157409402 cites W2327540181 @default.
- W2157409402 cites W2950486872 @default.
- W2157409402 cites W2082331975 @default.
- W2157409402 doi "https://doi.org/10.1016/j.jorganchem.2011.10.028" @default.
- W2157409402 hasPublicationYear "2012" @default.
- W2157409402 type Work @default.
- W2157409402 sameAs 2157409402 @default.
- W2157409402 citedByCount "40" @default.
- W2157409402 countsByYear W21574094022012 @default.
- W2157409402 countsByYear W21574094022013 @default.
- W2157409402 countsByYear W21574094022014 @default.
- W2157409402 countsByYear W21574094022015 @default.
- W2157409402 countsByYear W21574094022016 @default.
- W2157409402 countsByYear W21574094022017 @default.
- W2157409402 countsByYear W21574094022018 @default.
- W2157409402 countsByYear W21574094022019 @default.
- W2157409402 countsByYear W21574094022020 @default.
- W2157409402 countsByYear W21574094022021 @default.
- W2157409402 crossrefType "journal-article" @default.
- W2157409402 hasAuthorship W2157409402A5001288879 @default.
- W2157409402 hasAuthorship W2157409402A5008205291 @default.
- W2157409402 hasAuthorship W2157409402A5035727683 @default.
- W2157409402 hasAuthorship W2157409402A5045013701 @default.
- W2157409402 hasAuthorship W2157409402A5046393755 @default.