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• W2157529154 abstract "A catalyst system generated in situ from bis(2-methallyl)-cycloocta-1,5-diene-ruthenium(II) and a phosphine was found to efficiently catalyze the addition of thioamides to terminal alkynes with exclusive formation of the anti-Markovnikov thioenamide products. The stereoselectivity of the addition is usually high and controlled by the choice of the phosphine ligand, whereas the (E)-isomers are predominantly formed in the presence of tri(n-octyl)phosphine, the use of bis(dicyclohexylphosphino)methane preferentially leads to the formation of the (Z)-configured thioenamides." @default.
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• W2157529154 date "2008-09-19" @default.
• W2157529154 modified "2023-09-27" @default.
• W2157529154 title "Ruthenium-Catalyzed Stereoselective anti-Markovnikov-Addition of Thioamides to Alkynes" @default.
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• W2157529154 doi "https://doi.org/10.1021/ol801736h" @default.
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