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• W2157631425 abstract "A new and stable nitroso-nitro-enamine reagent, providing a nitrile oxide 1,3-dipole, has been treated with dipolarophiles in the course of 1,3-dipolar cycloaddition reactions to give a large number of novel isoxazolyl-pyrroline derivatives. Surprisingly, instead of the expected 2-isoxazolyl-dihydropyrrole cycloadducts, dihydropyrrol-3-one oximes were isolated as the main products in most cases. The imino-oxime moiety was successfully transformed into 3-aminopyrrole derivatives. The mechanism and selectivity of the reactions were also studied by experimental and theoretical methods [WB97XD/6-311++G(2d,2p)//B3LYP/6-311++G(2d,2p)], including the solvent effect." @default.
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• W2157631425 date "2015-09-29" @default.
• W2157631425 modified "2023-10-18" @default.
• W2157631425 title "Synthesis of Isoxazoline Derivatives Based on Nitrile Oxide Cycloaddition of Nitroso-Nitro-Enamine" @default.
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• W2157631425 doi "https://doi.org/10.1002/ejoc.201500905" @default.
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