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- W2157674720 abstract "Free sugar radicals. V. Deoxyhydroxylaminosugar derivatives and related compoundsWe describe several synthetic routes to deoxyhydroxylaminosugar derivatives of the type Glyc-N(OH)-R where Glyc stands for a sugar moiety linked by any of its C-atoms except the anomeric one and R for one of the following substituants: H-atom, acyl, phosphoryl groups, aminoacid or sugar residues.Compounds of the above structure are potentially close analogs, homoisosteres, NOH replacing O, of biochemically important molecules. Under aerobic conditions, solutions of these derivatives contain minute concentrations of the corresponding nitroxide radicals which do not decrease significantly the resolution of the NMR. spectra but render these compounds usable as a new kind of spin labels. Spectroscopic properties (1H-NMR., 13C-NMR., ESR.) of some of these compounds are reported." @default.
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- W2157674720 date "1982-07-28" @default.
- W2157674720 modified "2023-09-27" @default.
- W2157674720 title "Radicaux libres dérivés de sucres. V. Dérivés d'osamines N-hydroxylées et composés voisins Communication préliminaire" @default.
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- W2157674720 doi "https://doi.org/10.1002/hlca.19820650512" @default.
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