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- W2157701045 abstract "The readily available methylated pyrano[3,4-b]indol-3-ones 1a and 1b were hydrolyzed to furnish the 2-acetylindol-3-alkanoic acids 2 and 4. Compound 2 was easily transformed selectively to 2-acetyl-3-methylindole (3, salvadoricine). Substrate 1b reacts with molecular oxygen from the air only in the presence of a catalyst to give 2,3-diacetylindole (5) while 1a reacts with nitrosobenzene via a proposed Diels-Alder step to yield 2-acetylindole-3-carbaldehyde (6). The latter product can also be obtained in low yield from the reaction of 1a with molecular oxygen from the air." @default.
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- W2157701045 date "1992-01-01" @default.
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- W2157701045 title "First transformations of pyrano[3,4-b]indol-3-ones to salvadoricine and 2,3-diacylindoles" @default.
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- W2157701045 doi "https://doi.org/10.1002/jhet.5570290126" @default.
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