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- W2157833356 abstract "The crystal structure of the new compound Co7(TeO3)4Br6 is described together with the magnetic properties. The new compound crystallizes in the monoclinic space group C2/c with the unit cell parameters a=20.6532(5)Å, b=8.6533(2)Å, c=14.7262(5)Å, β=124.897(3)°, Z=4. The crystal structure was solved from single crystal data, R=0.0242. The structure can be considered as layered and the building units are [CoO4Br2] and [CoO2Br4] octahedra and [TeO3E] tetrahedra, E being the 5s2 lone pair on the Te(IV) ions. The magnetic properties of the compound are characterised by antiferromagnetic correlations at high temperatures, strong deviation from the Curie–Weiss behaviour in a broad intermediate temperature range and long range magnetic ordering setting-in at low temperatures. Magnetic ordering takes place in stages, being represented by two susceptibility anomalies, at TN=33K and TC=27K. The magnetic transition at TC is ferromagnetic (or ferrimagnetic) in character." @default.
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- W2157833356 date "2006-07-01" @default.
- W2157833356 modified "2023-10-06" @default.
- W2157833356 title "Crystal structure and magnetic properties of Co7(TeO3)4Br6—a new cobalt tellurite bromide" @default.
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- W2157833356 doi "https://doi.org/10.1016/j.solidstatesciences.2006.03.004" @default.
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