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- W2157940487 abstract "A new singly charged pyridinium axle was prepared and combined with disulfonated dibenzo[24]crown-8 ether to form a [2]pseudorotaxane. The reaction of this new, anionic ligand with Zn(II) ions, under various crystallization conditions, resulted in the formation of three metal-organic rotaxane framework (MORF) solids; a one-periodic ML coordination polymer and two, two-periodic ML(2) square grid frameworks. The layers of square grids can be pillared to create full three-periodic MORF structures, which have completely neutral frameworks and are porous. These three-periodic materials represent the first examples of neutral porous MOFs in which one (or more) of the linkers is a mechanically interlocked molecule (MIM)." @default.
- W2157940487 created "2016-06-24" @default.
- W2157940487 creator A5030819950 @default.
- W2157940487 creator A5045495479 @default.
- W2157940487 date "2010-11-23" @default.
- W2157940487 modified "2023-09-28" @default.
- W2157940487 title "One-, Two- and Three-Periodic Metal-Organic Rotaxane Frameworks (MORFs): Linking Cationic Transition-Metal Nodes with an Anionic Rotaxane Ligand" @default.
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- W2157940487 doi "https://doi.org/10.1002/chem.201002542" @default.
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