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- W2158043532 abstract "A sub-melting-temperature exotherm in a polyamide-6/clay nanocomposite (containing 3 wt % montmorillonite) was investigated with differential scanning calorimetry. It existed only via air-quenching from the melt; it did not exist at higher or lower heating rates. The exotherm could be ascribed to frozen-in stresses in the interlamellar regions through hydrogen bonding. A combination of larger internal stresses and larger crystallinity was necessary to produce this exotherm. Its appearance was closely connected to the addition of montmorillonite. During the air-quenching process, montmorillonite not only greatly accelerated the crystallization rate of polyamide-6 but also further intensified the internal stresses produced during the quenching process. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 378–382, 2005" @default.
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- W2158043532 date "2005-01-01" @default.
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- W2158043532 title "Investigation of the sub-melting-temperature exotherm in melt-quenched polyamide-6/clay nanocomposites" @default.
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- W2158043532 doi "https://doi.org/10.1002/polb.20339" @default.
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