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- W2158062011 abstract "A one-pot, four-component, efficient, and facile synthesis of highly functionalized benzimidazo[2,1-b][1,3]thiazines promoted by ionic liquid ([bmim]Br)/Et3N has been developed. The protocol involves nucleophilic addition of o-phenylenediamine to carbon disulfide to give 2-mercaptobenzimidazole. After nucleophilic addition to the activated olefinic bond of a zwitterionic intermediate, which is generated by reaction of isocyanide with an electrophilic alkyne, subsequent cyclization gives benzimidazo[2,1-b][1,3]thiazines with high atom economy. The ionic liquid was recovered and reused without any appreciable decrease in activity and product yield." @default.
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- W2158062011 date "2013-05-31" @default.
- W2158062011 modified "2023-09-26" @default.
- W2158062011 title "Ionic-liquid-promoted Four-component One-pot Synthesis of Highly Functionalized Benzimidazo[2,1-<i>b</i>][1,3]thiazines: Facile Construction of<i>N-</i>fused Heterocycles" @default.
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- W2158062011 doi "https://doi.org/10.1002/ajoc.201300049" @default.
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