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- W2158067611 abstract "Treatment of Zn(II) and Cd(II) hydroxide complexes of the tris(2-pyridylmethyl)amine (TPA) ligand with COS or CS2 in protic solvents (MeOH or EtOH) resulted in [(TPA)Zn–SC(S)OCH3]ClO4 (1), [(TPA)Zn– SC(O)OCH3]BF4 (2), [(TPA)Zn–SC(O)OCH3]ClO4 (3), [(TPA)Zn–SC(O)OCH2CH3]BF4 (4), [(TPA)Cd– SC(S)OCH3]ClO4 (5) and [(TPA)Cd–SC(O)OCH3]ClO4 (6). The molecular structures of 1, 2, 5 and 6 were determined by X-ray crystallography. Complexes 2, 3 and 4, unlike 1, 5 and 6, are easily hydrolyzed upon treatment with water in CH3CN to give zinc hydrosulfide complexes of the form [(TPA)Zn–SH]X (X = BF4" @default.
- W2158067611 created "2016-06-24" @default.
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- W2158067611 date "2012-05-01" @default.
- W2158067611 modified "2023-10-18" @default.
- W2158067611 title "Synthesis of zinc and cadmium O-alkyl thiocarbonate and dithiocarbonate complexes and a cationic zinc hydrosulfide complex" @default.
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- W2158067611 doi "https://doi.org/10.1016/j.ica.2012.01.040" @default.
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