FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2158100403> ?p ?o ?g. }

• W2158100403 endingPage "8590" @default.
• W2158100403 startingPage "8583" @default.
• W2158100403 abstract "Abstract An isolated silver(I) ammonia monomer, a dimer, and a novel dimer containing an intercalated water molecule have been embedded as guests in supramolecular frameworks, [Ag(NH 3 ) 2 ][(H 2 thpe)(H 3 thpe)] ⋅ MeCN ( 1 ), [{Ag(NH 3 ) 2 } 2 ][(H 2 thpe) 2 ] ⋅ 4.25 H 2 O ( 2 ), and [{Ag(NH 3 ) 2 }‐H 2 O‐{Ag(NH 3 ) 2 }][(H 2 thpe) 2 ] ⋅ benzene ( 3 ) (H 3 THPE=tris(hydroxyphenyl)ethane). The [{Ag(NH 3 ) 2 } 2 ] 2+ dimer is not stable as an isolated entity, but is stabilized by hydrogen bonding in the supramolecular framework. The water‐intercalated silver(I) ammonia dimer, which constitutes a novel species, is also subject by hydrogen bonding in concentrated solutions. The destabilization energy of the dimer relative to isolated monomers is calculated to be ≈300 kJ mol −1 by both perturbation methods and DFT theory. For the water‐intercalated dimer it is calculated to be ≈200 kJ mol −1 according to the BSSE‐corrected MP2 calculation. The different aggregate states show a dramatic variation of absorption and emission properties, in accordance with the concentration dependent red‐shift observed in solutions. Natural‐bond‐orbital analysis shows that the disilver‐ammonium‐aquo “sandwich” cation in 3 is stabilized by interaction between the π lone pair orbital on the oxygen atom of the water molecule and Ag I N σ antibonding molecular orbital." @default.
• W2158100403 created "2016-06-24" @default.
• W2158100403 creator A5036001834 @default.
• W2158100403 creator A5061099667 @default.
• W2158100403 creator A5083062800 @default.
• W2158100403 creator A5084865051 @default.
• W2158100403 date "2007-10-02" @default.
• W2158100403 modified "2023-10-17" @default.
• W2158100403 title "The Nature of the AgI⋅⋅⋅AgI Interaction in Different Ag(NH3)2 Dimers Embedded in Supramolecular Solids" @default.
• W2158100403 cites W1547223276 @default.
• W2158100403 cites W1964517560 @default.
• W2158100403 cites W1964660092 @default.
• W2158100403 cites W1965272987 @default.
• W2158100403 cites W1972419413 @default.
• W2158100403 cites W1972498651 @default.
• W2158100403 cites W1972646318 @default.
• W2158100403 cites W1976404676 @default.
• W2158100403 cites W1984209389 @default.
• W2158100403 cites W1987776670 @default.
• W2158100403 cites W1990036255 @default.
• W2158100403 cites W1992218139 @default.
• W2158100403 cites W1992340715 @default.
• W2158100403 cites W2000126507 @default.
• W2158100403 cites W2000872531 @default.
• W2158100403 cites W2008205625 @default.
• W2158100403 cites W2008797813 @default.
• W2158100403 cites W2014012031 @default.
• W2158100403 cites W2018191649 @default.
• W2158100403 cites W2021746019 @default.
• W2158100403 cites W2023048616 @default.
• W2158100403 cites W2026228805 @default.
• W2158100403 cites W2034519399 @default.
• W2158100403 cites W2034903738 @default.
• W2158100403 cites W2042229177 @default.
• W2158100403 cites W2044682544 @default.
• W2158100403 cites W2048204405 @default.
• W2158100403 cites W2050905799 @default.
• W2158100403 cites W2061931740 @default.
• W2158100403 cites W2062594477 @default.
• W2158100403 cites W2065974186 @default.
• W2158100403 cites W2066917452 @default.
• W2158100403 cites W2071398165 @default.
• W2158100403 cites W2074933065 @default.
• W2158100403 cites W2085019299 @default.
• W2158100403 cites W2087701051 @default.
• W2158100403 cites W2088204832 @default.
• W2158100403 cites W2090107479 @default.
• W2158100403 cites W2090689576 @default.
• W2158100403 cites W2090757385 @default.
• W2158100403 cites W2092443292 @default.
• W2158100403 cites W2103191961 @default.
• W2158100403 cites W2104037784 @default.
• W2158100403 cites W2105373947 @default.
• W2158100403 cites W2108431697 @default.
• W2158100403 cites W2109141843 @default.
• W2158100403 cites W2110570691 @default.
• W2158100403 cites W2115125051 @default.
• W2158100403 cites W2117353357 @default.
• W2158100403 cites W2130603908 @default.
• W2158100403 cites W2132003168 @default.
• W2158100403 cites W2135261637 @default.
• W2158100403 cites W2144262857 @default.
• W2158100403 cites W2147803622 @default.
• W2158100403 cites W2148363281 @default.
• W2158100403 cites W2150315155 @default.
• W2158100403 cites W2150345533 @default.
• W2158100403 cites W2154774781 @default.
• W2158100403 cites W2155742788 @default.
• W2158100403 cites W2165244519 @default.
• W2158100403 cites W2170012858 @default.
• W2158100403 cites W2416131396 @default.
• W2158100403 cites W2949091020 @default.
• W2158100403 cites W4214620161 @default.
• W2158100403 cites W4230473086 @default.
• W2158100403 doi "https://doi.org/10.1002/chem.200700577" @default.
• W2158100403 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17659514" @default.
• W2158100403 hasPublicationYear "2007" @default.
• W2158100403 type Work @default.
• W2158100403 sameAs 2158100403 @default.
• W2158100403 citedByCount "28" @default.
• W2158100403 countsByYear W21581004032012 @default.
• W2158100403 countsByYear W21581004032013 @default.
• W2158100403 countsByYear W21581004032014 @default.
• W2158100403 countsByYear W21581004032015 @default.
• W2158100403 countsByYear W21581004032018 @default.
• W2158100403 countsByYear W21581004032019 @default.
• W2158100403 crossrefType "journal-article" @default.
• W2158100403 hasAuthorship W2158100403A5036001834 @default.
• W2158100403 hasAuthorship W2158100403A5061099667 @default.
• W2158100403 hasAuthorship W2158100403A5083062800 @default.
• W2158100403 hasAuthorship W2158100403A5084865051 @default.
• W2158100403 hasConcept C112887158 @default.
• W2158100403 hasConcept C115624301 @default.
• W2158100403 hasConcept C121332964 @default.
• W2158100403 hasConcept C130188946 @default.
• W2158100403 hasConcept C139358910 @default.
• W2158100403 hasConcept C147120987 @default.
• W2158100403 hasConcept C166940927 @default.

• next