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- W2158200712 abstract "The structure and reactivity of high-valent FeVO and MnVIO oxidation catalysts containing a polyoxometalate [PW11O39]7− lacunary ligand (2) have been investigated by a computational study. Calculations have demonstrated there is an intriguing analogy between these species and the active species (1) of the enzyme cytochrome P450 (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z53867_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2158200712 date "2004-10-20" @default.
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- W2158200712 title "Computer-Generated High-Valent Iron-Oxo and Manganese-Oxo Species with Polyoxometalate Ligands: How do they Compare with the Iron-Oxo Active Species of Heme Enzymes?" @default.
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- W2158200712 doi "https://doi.org/10.1002/anie.200453867" @default.
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