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- W2158202354 abstract "By low-temperature scanning tunneling microscopy, we study CO molecule chemisorption on a quasi-one-dimensional Cu(110)-(2×1)-O surface. Atom-resolved images reveal how the interaction of CO with the surface Cu-O- chains gives rise to orthogonal attractive and repulsive intermolecular interactions. First-principles calculations show that CO molecules induce unprecedented lifting of the host Cu atoms by 1 Å from the Cu-O- chains, enabling the Cu-CO unit to tilt by 45° from the surface normal. Contrary to the behavior of CO on metal surfaces, this structural distortion enables unprecedented, orthogonal, short-range intermolecular dipole-dipole attraction and long-range, surface-mediated repulsion. These interactions lead to self-assembly into molecular nanograting structures consisting of arrays of single-molecule-wide CO rows. The origin of the novel behavior of CO molecules in the electronic and geometrical properties of the quasi-one-dimensional substrate suggests that similar molecule-molecule and molecule-substrate interactions could play an important role at catalytic sites on reactive surfaces." @default.
- W2158202354 created "2016-06-24" @default.
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- W2158202354 date "2012-05-05" @default.
- W2158202354 modified "2023-09-25" @default.
- W2158202354 title "Orthogonal Intermolecular Interactions of CO Molecules on a One-Dimensional Substrate" @default.
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- W2158202354 doi "https://doi.org/10.1146/annurev-physchem-032210-103353" @default.
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