FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2158209511> ?p ?o ?g. }

• W2158209511 endingPage "10918" @default.
• W2158209511 startingPage "10913" @default.
• W2158209511 abstract "The all-ferrous Rieske cluster, [2Fe-2S] 0 , has been produced in solution and characterized by protein-film voltammetry and UV–visible, EPR, and Mössbauer spectroscopies. The [2Fe-2S] 0 cluster, in the overexpressed soluble domain of the Rieske protein from the bovine cytochrome bc 1 complex, is formed at –0.73 V at pH 7. Therefore, at pH 7, the [2Fe-2S] 1+/0 couple is 1.0 V below the [2Fe-2S] 2+/1+ couple. The two cluster-bound ferrous irons are both high spin (S = 2), and they are coupled antiferromagnetically (– J ≥ 30 cm –1 , H =–2 J S1·S2) to give a diamagnetic (S = 0) ground state. The ability of the Rieske cluster to exist in three oxidation states (2+, 1+, and 0) without an accompanying coupled reaction, such as a conformational change or protonation, is highly unusual. However, uncoupled reduction to the [2Fe-2S] 0 state occurs at pH > 9.8 only, and at high pH the intact cluster persists in solution for <1 min. At pH < 9.8, the all-ferrous cluster is stabilized significantly by protonation. A combination of experimental data and calculations based on density functional theory suggests strongly that the proton binds to one of the cluster μ 2 -sulfides, consistent with observations that reduced [3Fe-4S] clusters are protonated also. The implications for our understanding of coupled reactions at iron–sulfur clusters and of the factors that determine the relative stabilities of their different oxidation states are discussed." @default.
• W2158209511 created "2016-06-24" @default.
• W2158209511 creator A5015898609 @default.
• W2158209511 creator A5034202204 @default.
• W2158209511 creator A5041351975 @default.
• W2158209511 creator A5056046836 @default.
• W2158209511 creator A5090355454 @default.
• W2158209511 date "2004-07-19" @default.
• W2158209511 modified "2023-10-03" @default.
• W2158209511 title "Formation and characterization of an all-ferrous Rieske cluster and stabilization of the [2Fe-2S] ⁰ core by protonation" @default.
• W2158209511 cites W100440637 @default.
• W2158209511 cites W1517224738 @default.
• W2158209511 cites W1581910437 @default.
• W2158209511 cites W1966657114 @default.
• W2158209511 cites W1968500322 @default.
• W2158209511 cites W1971290102 @default.
• W2158209511 cites W1974086171 @default.
• W2158209511 cites W1975882924 @default.
• W2158209511 cites W1980660688 @default.
• W2158209511 cites W1985636683 @default.
• W2158209511 cites W1988124219 @default.
• W2158209511 cites W1991784744 @default.
• W2158209511 cites W1997662072 @default.
• W2158209511 cites W2004240895 @default.
• W2158209511 cites W2004538890 @default.
• W2158209511 cites W2004583631 @default.
• W2158209511 cites W2005341395 @default.
• W2158209511 cites W2005692769 @default.
• W2158209511 cites W2008711518 @default.
• W2158209511 cites W2009452434 @default.
• W2158209511 cites W2010265521 @default.
• W2158209511 cites W2016183638 @default.
• W2158209511 cites W2027264849 @default.
• W2158209511 cites W2027475750 @default.
• W2158209511 cites W2038205004 @default.
• W2158209511 cites W2042899008 @default.
• W2158209511 cites W2044946482 @default.
• W2158209511 cites W2061407935 @default.
• W2158209511 cites W2066802149 @default.
• W2158209511 cites W2072425078 @default.
• W2158209511 cites W2090079874 @default.
• W2158209511 cites W2094188910 @default.
• W2158209511 cites W2129818993 @default.
• W2158209511 cites W2165886769 @default.
• W2158209511 cites W26283934 @default.
• W2158209511 cites W95436999 @default.
• W2158209511 doi "https://doi.org/10.1073/pnas.0402711101" @default.
• W2158209511 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/503719" @default.
• W2158209511 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15263097" @default.
• W2158209511 hasPublicationYear "2004" @default.
• W2158209511 type Work @default.
• W2158209511 sameAs 2158209511 @default.
• W2158209511 citedByCount "42" @default.
• W2158209511 countsByYear W21582095112012 @default.
• W2158209511 countsByYear W21582095112013 @default.
• W2158209511 countsByYear W21582095112014 @default.
• W2158209511 countsByYear W21582095112015 @default.
• W2158209511 countsByYear W21582095112016 @default.
• W2158209511 countsByYear W21582095112017 @default.
• W2158209511 countsByYear W21582095112018 @default.
• W2158209511 countsByYear W21582095112019 @default.
• W2158209511 countsByYear W21582095112020 @default.
• W2158209511 countsByYear W21582095112021 @default.
• W2158209511 countsByYear W21582095112023 @default.
• W2158209511 crossrefType "journal-article" @default.
• W2158209511 hasAuthorship W2158209511A5015898609 @default.
• W2158209511 hasAuthorship W2158209511A5034202204 @default.
• W2158209511 hasAuthorship W2158209511A5041351975 @default.
• W2158209511 hasAuthorship W2158209511A5056046836 @default.
• W2158209511 hasAuthorship W2158209511A5090355454 @default.
• W2158209511 hasBestOaLocation W21582095111 @default.
• W2158209511 hasConcept C121332964 @default.
• W2158209511 hasConcept C145148216 @default.
• W2158209511 hasConcept C164866538 @default.
• W2158209511 hasConcept C178790620 @default.
• W2158209511 hasConcept C179104552 @default.
• W2158209511 hasConcept C181199279 @default.
• W2158209511 hasConcept C185592680 @default.
• W2158209511 hasConcept C187961010 @default.
• W2158209511 hasConcept C199360897 @default.
• W2158209511 hasConcept C2775832776 @default.
• W2158209511 hasConcept C2777852564 @default.
• W2158209511 hasConcept C2778591166 @default.
• W2158209511 hasConcept C30095370 @default.
• W2158209511 hasConcept C41008148 @default.
• W2158209511 hasConcept C46141821 @default.
• W2158209511 hasConcept C544153396 @default.
• W2158209511 hasConcept C55493867 @default.
• W2158209511 hasConcept C55904794 @default.
• W2158209511 hasConcept C70854507 @default.
• W2158209511 hasConcept C8010536 @default.
• W2158209511 hasConceptScore W2158209511C121332964 @default.
• W2158209511 hasConceptScore W2158209511C145148216 @default.
• W2158209511 hasConceptScore W2158209511C164866538 @default.
• W2158209511 hasConceptScore W2158209511C178790620 @default.
• W2158209511 hasConceptScore W2158209511C179104552 @default.
• W2158209511 hasConceptScore W2158209511C181199279 @default.
• W2158209511 hasConceptScore W2158209511C185592680 @default.

• next