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- W2158356908 abstract "The kinetics of the disproportionation of N Cl-n-propylamine and N – Cl-isopropylamine to the corresponding N, N-dichloramines were found to be a second order with respect to the N-chloramine. The influence of amine concentration, pH, buffers, ionic strength, and temperature were also studied. The observed influence of pH supports a reaction mechanism which allowed estimation of the protonation constants of the chloramines studied. The influence of buffers, which was studied for both the above chloramines and N Cl-3-aminopropanol, reflects general acid catalysis, for which a mechanism is proposed. Bronsted's equation was fitted to the catalytic constants obtained therefrom so as to estimate the values of the parameter α for these three N-chloramines. © John Wiley & Sons, Inc." @default.
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- W2158356908 date "1992-11-01" @default.
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- W2158356908 title "Disproportionation kinetics of N ? Cl-n-propylamine and N ? Cl-isopropylamine" @default.
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- W2158356908 doi "https://doi.org/10.1002/kin.550241109" @default.
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