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• W2158392369 abstract "Random and block copolymers containing two different classes of hydrogen-bonding side-chains have been prepared by ring-opening metathesis polymerization. The resulting copolymers can be viewed as “universal polymer backbones” based solely on two competitive hydrogen-bonding pairs. The hydrogen-bonding side chains containing thymine and cyanuric acid-based recognition motifs are shown to self-assemble with their complementary diamido pyridine and isophthalic wedge moieties, respectively, even in the presence of competitive recognition sites, i.e., selective functionalization of the copolymers can be accomplished via a one-step orthogonal self-assembly approach displaying self-sorting in a competitive environment. These results clearly demonstrate the concept of self-sorting in synthetic polymers and suggest the design of complex polymeric materials containing competitive noncovalent interactions." @default.
• W2158392369 created "2016-06-24" @default.
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• W2158392369 date "2005-07-27" @default.
• W2158392369 modified "2023-10-02" @default.
• W2158392369 title "Self-Sorting in Polymers" @default.
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• W2158392369 doi "https://doi.org/10.1021/ma050755w" @default.
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