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• W2158474725 endingPage "13257" @default.
• W2158474725 startingPage "13253" @default.
• W2158474725 abstract "Abstract Chiral allylic alcohols of ω‐alkenoic acids and derivatives thereof are highly important building blocks for the synthesis of biologically active compounds. The direct enantioselective CH oxidation of linear terminal olefins offers the shortest route toward these compounds, but known synthetic methods are limited and suffer from low selectivities. Described herein is an enzymatic approach using the P450 BM3 monooxygenase mutant A74G/L188Q, which catalyzes allylic hydroxylation with high to excellent chemo‐ and enantioselectivities providing the desirable secondary alcohols." @default.
• W2158474725 created "2016-06-24" @default.
• W2158474725 creator A5082588098 @default.
• W2158474725 creator A5090548096 @default.
• W2158474725 creator A5003661348 @default.
• W2158474725 date "2014-08-27" @default.
• W2158474725 modified "2023-10-18" @default.
• W2158474725 title "Enantioselective Allylic Hydroxylation of ω-Alkenoic Acids and Esters by P450 BM3 Monooxygenase" @default.
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• W2158474725 doi "https://doi.org/10.1002/anie.201403537" @default.
• W2158474725 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25164074" @default.
• W2158474725 hasPublicationYear "2014" @default.
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