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- W2158542004 abstract "An analytical LCAO MO perturbation approach has been developed for treating the electronic structure and some properties of Y-shaped EL3 compounds where E is a main group element A or a transition metal M. Three problems have been considered: (i) the relative strengths of E-L(1,2) (1 and 2 stand for the paired ligands) and E-L(3) (3 stands for the unique ligand) bonds; (ii) the mutual influence of ligands in substituted complexes EL2L′; (iii) the site preference of the stronger donor (or acceptor) of substituents L′, L″. Ratios of overlap populations T=N E-L(3)/N E-L(1) were estimated for ns, np and (n−1)d contributions. For 6–10 valence electron AL3 we found T (s)>1, T (p)>1. These contributions all reinforce to make the A-L(3) bond relatively stronger than A-L(1,2) bonds. The ML3 d0–d8 case was also examined and it was found that T (s+p+d)>1, while the T (p) contribution dominates in ML3 (d10) complexes to make M-L(3)>M-L(1,2). The perturbing influence on ligand σ orbital energies δα′=α(L′)−α(L), where ..." @default.
- W2158542004 created "2016-06-24" @default.
- W2158542004 creator A5040427661 @default.
- W2158542004 date "1993-12-10" @default.
- W2158542004 modified "2023-09-28" @default.
- W2158542004 title "Relative strengths of axial and equatorial bonds and site preferences for ligand substitution in σ-bonded T-shapedEL3complexes" @default.
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- W2158542004 doi "https://doi.org/10.1080/00268979300102991" @default.
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