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- W2158593312 abstract "The bands with Iv < 13 eV in the photoelectron spectra of quinoline (IX), isoquinoline (X), cinnoline (XI), quinazoline (XII), and quinoxaline (XIII) have been reassigned in a way consistent with the assignment proposed for pyridine (II), the diazines (III, IV, V), s-triazine (VI), and 1,2,4,5-tetrazine (VII). The bands corresponding to the ejection of an electron from a π-orbital have been identified by a regression calculation based on a HMO perturbation treatment. It has been found that the combined through-space and through-bond interaction of the lone pairs in III, IV, V and in their corresponding benzologues XI, XII, XIII are the same within experimental error ( ±, 0.2 eV). Our assignment is also supported by an empirical correlation of the pKa, 1− values and the mean lone-pair ionization potentials of the azaderivatives I to XIII." @default.
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- W2158593312 date "1972-01-31" @default.
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- W2158593312 title "Photoelectron Spektra of Azabenzenes and Azanaphthalenes: II. A Reinvestigation of Azanaphthalenes by High-Resolution Photoelectron Spectroscopy" @default.
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- W2158593312 doi "https://doi.org/10.1002/hlca.19720550131" @default.
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