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• W2158606108 abstract "The Fourier transform infrared and Raman spectra of di-i-propoxyphosphoryl benzylisothiourea (DPB) (1) in the solid state and in solutions of CCl4, CHCl3, CHBr3, CH2Cl2, C2H4Cl2, C2H4Br2 and THF were studied. In the IR spectra, the effects of different concentrations were also investigated. The behavior of the ν(NH), δ(NH), δ(HNH), ν(CN) and ν(PO) normal modes suggests the existence of a tautomerism between the phosphorylamine (I) and N-phosphorylimine (II) structures:Download : Download full-size imageThe data show the presence of different δ(NH) and δ(HNH) bendings and ν(CN) normal modes in the solid state as a result of inter and intramolecular hydrogen bonding. The experimental approximate frequencies assignments were done for this compound, and were confirmed by a normal coordinate analysis carried out for several fragments of phosphorylamine and N-phosphorylimine structures." @default.
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• W2158606108 date "2000-03-01" @default.
• W2158606108 modified "2023-09-28" @default.
• W2158606108 title "A vibrational study of di-i-propoxyphosphoryl benzylisothiourea" @default.
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• W2158606108 doi "https://doi.org/10.1016/s1386-1425(99)00178-x" @default.
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