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- W2158656825 abstract "Pentose sugars, such as ribose and arabinose, easily graft polylysine to polyarginine by means of the Maillard reaction, resulting in water soluble or insoluble block copolymers, depending on the starting concentrations of the reactants. Soluble block copolymers prepared by this method have a molecular weight of no lower than 200,000 g/mol, whereas the original homopeptide molecular weights were less than 50,000 g/mol. The water soluble copolymer complexes with the red-violet anionic cluster of copper and penicillamine at pH 8.8, although with progressive dissociation into the unaltered copolymer and unaltered cluster anion, whereas suspensions of an insoluble version of the copolymer, with the lysine/arginine molar ratio near 30/70, exhibited a strong affinity for the same copper cluster. Because of its lysine content, a copolymer of the latter type is easily biotinylated. Biotinylated and complexed with the copper cluster, the copolymer might be of interest as a biologically selective carrier for delivering copper radionuclides by using affinity targeting methods. © 2003 Oklahoma Academy of Science" @default.
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- W2158656825 date "2015-02-17" @default.
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- W2158656825 title "Linking Poly-L-arginine To Poly-DL-lysine By Using The Maillard Reaction: A Block Copolymer That Binds The Cluster Anion of Copper and Penicillamine" @default.
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