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- W2158665497 abstract "1,4-Remote stereocontrol is established through double asymmetric induction in asymmetric catalytic glyoxylate-ene reaction, by simple combination of the chirality of homoallytic ethers and binapthol-titanium catalyst. The present approach to 1,4-remote stereocontrol can be applied to the asymmetric synthesis of the diastereomeric (11R,14S)-anti- and (31R,34S)-syn-fragments of an immunosuppressant rapamycin with remote relationships of Me and OH groupings." @default.
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- W2158665497 title "1,4-Remote stereocontrol by asymmetric catalytic carbonyl-ene reaction with chiral homoallylic ethers: An application to the asymmetric synthesis od (11R,14S)-anti- and (31R,34S)-syn-segements of immunosuppressant rapamycin" @default.
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- W2158665497 doi "https://doi.org/10.1016/0040-4039(94)80120-7" @default.
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