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• W2158690475 abstract "The effects of a cationic surfactant, cetyltrimethylammonium bromide (CTAB), on the gelation of methylcellulose (MC) in aqueous solutions have been investigated by micro differential scanning calorimetry (micro DSC) and rheology. Methylcellulose had a weight average molecular weight of 310 000 and a degree of substitution of 1.8. The concentration of MC was kept at 0.5 wt % (0.016 mM) and 1 wt % (0.032 mM), and the concentration of CTAB in the MC solutions was varied from 0 to 0.6 wt % (16.5 mM). Upon heating, a single endothermic peak, which is due to the hydrophobic association and gelation of MC, shifts to lower temperatures with increasing CTAB for CTAB ≤ CMC (0.93 mM or 0.034 wt %), and then it shifts to higher temperatures lineally with CTAB for CTAB > CMC. At the same time, the endothermic enthalpy decreases with increasing CTAB concentration. Even though CTAB shows a significant “salt-in” effect on the gelation of MC, it does not affect the pattern of the sol−gel transition as well as the gel strength of MC. At the highest concentration of CTAB, 0.60 wt %, MC is still able to form a gel. At a given ratio of CTAB/MC, the effect of CTAB on MC becomes stronger when the MC concentration is lower. The results for the MC−CTAB system are compared with an ionic surfactant, SDS and the significant differences in affecting the gelation of MC between two surfactants are recognized." @default.
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• W2158690475 date "2007-05-22" @default.
• W2158690475 modified "2023-10-18" @default.
• W2158690475 title "Micro-DSC and Rheological Studies of Interactions between Methylcellulose and Surfactants" @default.
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• W2158690475 doi "https://doi.org/10.1021/jp0712957" @default.
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