Matches in SemOpenAlex for { <https://semopenalex.org/work/W2159032034> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2159032034 endingPage "947" @default.
- W2159032034 startingPage "943" @default.
- W2159032034 abstract "Abstract The Pt/C catalyzed hydrosilylation of Si 8 O 12 (CH=CH 2 ) 8 and 8 equiv of HSiMe 2 Cl produced Si 8 O 12 (CH 2 CH 2 SiMe 2 Cl) 8 that was de‐hydrochlorinated with 4 equiv of Z ‐HOCH 2 CH 2 =CHCH 2 OH in the presence of excess TMEDA. This preparation resulted in the attachment of four surface bridges (‐CH 2 CH 2 SiMe 2 OCH 2 CH=CHCH 2 OSiMe 2 CH 2 CH 2 ‐ Z ‐) on the quasi‐cube Si 8 O 12 framework. As a parallel study, the theoretical calculations of Si 8 O 12 (‐CH 2 CH 2 SiH 2 OCH 2 CH=HCH 2 OSiH 2 CH 2 CH 2 ‐ Z ‐) 4 were carried out at PM3 semi‐empirical level to find optimized geometries for use in four subsequent ab initio computations using standard basis sets of 3–21G* and 6–31G*. The calculations suggest that one should expect about equimolar mixture of the tetra‐adducts produced by the bridging over the edges of the quasi‐cube, either over four parallel edges or over two orthogonal pairs of parallel edges, but not by bridging across the faces of the quasi‐cube." @default.
- W2159032034 created "2016-06-24" @default.
- W2159032034 creator A5013335320 @default.
- W2159032034 creator A5014403694 @default.
- W2159032034 creator A5042845233 @default.
- W2159032034 creator A5076963678 @default.
- W2159032034 date "2002-10-01" @default.
- W2159032034 modified "2023-10-16" @default.
- W2159032034 title "Octasilsesquioxane Chemistry I. Attachment of Four Surface Bridges to Octasilsesquioxane Quasi-cube Framework" @default.
- W2159032034 cites W161087372 @default.
- W2159032034 cites W1972435556 @default.
- W2159032034 cites W1981753468 @default.
- W2159032034 cites W1987332914 @default.
- W2159032034 cites W1987582467 @default.
- W2159032034 cites W1999362227 @default.
- W2159032034 cites W2000287575 @default.
- W2159032034 cites W2009614858 @default.
- W2159032034 cites W2023650387 @default.
- W2159032034 cites W2054894128 @default.
- W2159032034 cites W2074429477 @default.
- W2159032034 cites W2110199161 @default.
- W2159032034 cites W2119578867 @default.
- W2159032034 cites W2127898819 @default.
- W2159032034 cites W2131595456 @default.
- W2159032034 cites W2151563997 @default.
- W2159032034 cites W2167596488 @default.
- W2159032034 cites W4238824252 @default.
- W2159032034 doi "https://doi.org/10.1002/jccs.200200133" @default.
- W2159032034 hasPublicationYear "2002" @default.
- W2159032034 type Work @default.
- W2159032034 sameAs 2159032034 @default.
- W2159032034 citedByCount "2" @default.
- W2159032034 countsByYear W21590320342019 @default.
- W2159032034 crossrefType "journal-article" @default.
- W2159032034 hasAuthorship W2159032034A5013335320 @default.
- W2159032034 hasAuthorship W2159032034A5014403694 @default.
- W2159032034 hasAuthorship W2159032034A5042845233 @default.
- W2159032034 hasAuthorship W2159032034A5076963678 @default.
- W2159032034 hasConcept C108204754 @default.
- W2159032034 hasConcept C114614502 @default.
- W2159032034 hasConcept C147597530 @default.
- W2159032034 hasConcept C174348530 @default.
- W2159032034 hasConcept C178790620 @default.
- W2159032034 hasConcept C185592680 @default.
- W2159032034 hasConcept C2781442258 @default.
- W2159032034 hasConcept C31258907 @default.
- W2159032034 hasConcept C33923547 @default.
- W2159032034 hasConcept C41008148 @default.
- W2159032034 hasConcept C53051483 @default.
- W2159032034 hasConcept C71240020 @default.
- W2159032034 hasConcept C8010536 @default.
- W2159032034 hasConceptScore W2159032034C108204754 @default.
- W2159032034 hasConceptScore W2159032034C114614502 @default.
- W2159032034 hasConceptScore W2159032034C147597530 @default.
- W2159032034 hasConceptScore W2159032034C174348530 @default.
- W2159032034 hasConceptScore W2159032034C178790620 @default.
- W2159032034 hasConceptScore W2159032034C185592680 @default.
- W2159032034 hasConceptScore W2159032034C2781442258 @default.
- W2159032034 hasConceptScore W2159032034C31258907 @default.
- W2159032034 hasConceptScore W2159032034C33923547 @default.
- W2159032034 hasConceptScore W2159032034C41008148 @default.
- W2159032034 hasConceptScore W2159032034C53051483 @default.
- W2159032034 hasConceptScore W2159032034C71240020 @default.
- W2159032034 hasConceptScore W2159032034C8010536 @default.
- W2159032034 hasIssue "5" @default.
- W2159032034 hasLocation W21590320341 @default.
- W2159032034 hasOpenAccess W2159032034 @default.
- W2159032034 hasPrimaryLocation W21590320341 @default.
- W2159032034 hasRelatedWork W1986528257 @default.
- W2159032034 hasRelatedWork W1991616557 @default.
- W2159032034 hasRelatedWork W2016472295 @default.
- W2159032034 hasRelatedWork W2026948689 @default.
- W2159032034 hasRelatedWork W2047991101 @default.
- W2159032034 hasRelatedWork W2334792521 @default.
- W2159032034 hasRelatedWork W2341880960 @default.
- W2159032034 hasRelatedWork W2949918667 @default.
- W2159032034 hasRelatedWork W2951566524 @default.
- W2159032034 hasRelatedWork W4231499754 @default.
- W2159032034 hasVolume "49" @default.
- W2159032034 isParatext "false" @default.
- W2159032034 isRetracted "false" @default.
- W2159032034 magId "2159032034" @default.
- W2159032034 workType "article" @default.