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- W2159292003 abstract "A new method for the Rh(I)-catalyzed addition of arylboronic acids to N-tert-butanesulfinyl imino esters has been developed for the asymmetric synthesis of arylglycine derivatives. This method provides high yields (61−90%) and diastereoselectivities (>98:2) for a variety of functionalized arylboronic acids. The N-sulfinyl arylglycine ester products are versatile intermediates for further transformations, including selective protecting group removal, conversion to β-amino alcohols, and direct incorporation into peptides." @default.
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- W2159292003 date "2006-04-25" @default.
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- W2159292003 title "Asymmetric Synthesis of Protected Arylglycines by Rhodium-Catalyzed Addition of Arylboronic Acids to <i>N</i>-<i>tert</i>-Butanesulfinyl Imino Esters" @default.
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- W2159292003 doi "https://doi.org/10.1021/ja060529h" @default.
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