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- W2159339969 abstract "It was determined using X-ray photoelectron spectroscopy that Y zeolites, dealuminated with SiCl4 and exhibiting an AlSi ratio from 0.30 to 0.05, have an aluminium-rich surface. After dehydration at 790 K and subsequent readsorption of water at ambient temperature, the amount of Al in the surface of dealuminated Y zeolites slightly decreases, outer layers remaining still enriched in Al, while with the non-modified zeolite NH4Y this treatment results in appreciable Al deficiency of the surface. The acid leaching of NH4Y and NaM zeolites, using HCl solutions with pH ranging from 4 to 1, tends to remove more Al atoms from the surface than from the bulk. Under these conditions, the amorphization of NH4Y takes place." @default.
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- W2159339969 date "1985-03-01" @default.
- W2159339969 modified "2023-09-27" @default.
- W2159339969 title "Aluminium-to-silicon ratio on the surface of zeolites dealuminated using silicon tetrachloride vapour and acid leaching" @default.
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- W2159339969 doi "https://doi.org/10.1016/0144-2449(85)90074-0" @default.
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