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- W2159480124 abstract "Abstract A visible room‐temperature phosphorescence (RTP) signal, generated by complexation of cururbit[7]uril (CB[7]) and bromo‐substituted isoquinoline in aqueous solution, is employed to address the shuttling of a pH‐controlling molecular shuttle fabricated by CB[7] and a phosphor 6‐bromoisoquinoline derivative IQC[5] . The CB[7] host shuttles along the axial guest under acidic conditions, accompanied by a weak RTP emission signal, while deprotonation of the guest IQC[5] makes the CB[7] wheel locate on the phosphor group, leading to intense RTP emission. The switching RTP emission of the molecular shuttle, via pH adjusting, can be visibly identified by the naked eye. This is the first CB‐based molecular shuttle with an RTP signal as the output address of its shuttling and conformation." @default.
- W2159480124 created "2016-06-24" @default.
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- W2159480124 creator A5013468377 @default.
- W2159480124 creator A5033775618 @default.
- W2159480124 creator A5050844324 @default.
- W2159480124 date "2015-11-24" @default.
- W2159480124 modified "2023-10-15" @default.
- W2159480124 title "A Cucurbit[7]uril Based Molecular Shuttle Encoded by Visible Room-Temperature Phosphorescence" @default.
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- W2159480124 doi "https://doi.org/10.1002/cphc.201500901" @default.
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