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- W2159508426 abstract "Zirconacyclopentadienes reacted with electrophiles after treatment with alkyllithium. For example, the reaction with benzaldehyde after treatment with methyllithium to give a nucleophilic addition product of a dienyl moiety to aldehyde, dienylcarbinol, in a moderate yield. Similar reaction of a zirconacyclopentadiene using butyllithium with methyl methacrylate afforded a Michael addition product in a good yield. Treatment of zirconacyclopentadienes with n-BuLi followed by 1-bromo-2-butyne gave a mono-propargylated diene derivative in 95% yield after hydrolysis. When propargyl chloride was treated with n-BuLi first and then added to zirconacyclopentadienes, penta-substituted benzene derivatives were formed in high yields." @default.
- W2159508426 created "2016-06-24" @default.
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- W2159508426 date "2005-03-22" @default.
- W2159508426 modified "2023-09-26" @default.
- W2159508426 title "Reaction of Zirconacyclopentadienes with Electrophiles such as Benzaldehyde, Methyl Methacrylate and 1-Bromo-2-butyne After Treatment with RLi." @default.
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- W2159508426 doi "https://doi.org/10.1002/chin.200512065" @default.
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