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- W2159523735 abstract "Abstract An efficient and convenient α‐hydroxyallylation approach for the asymmetric synthesis of a variety of β‐amino‐α‐vinyl alcohols has been successfully developed. A wide range of vinylic amino alcohol derivatives could be obtained in very good yields and with excellent diastereomeric ratios of up to 99:1 in favor of anti isomers by highly diastereoselective Zn‐promoted benzoyloxyallylation of chiral N ‐ tert ‐butanesulfinyl imines with 3‐bromopropenyl benzoate at room temperature. In particular, excellent enantioinduction of the two new stereogenic centers was observed, with up to 98 % ee . The method provides a new route for the direct α‐hydroxyallylation of imines in a highly stereoselective manner. Moreover, the synthetic value of the method has also been demonstrated by the most concise and straightforward synthesis of (−)‐cytoxazone yet reported." @default.
- W2159523735 created "2016-06-24" @default.
- W2159523735 creator A5017353282 @default.
- W2159523735 creator A5043498660 @default.
- W2159523735 creator A5055998115 @default.
- W2159523735 creator A5072247998 @default.
- W2159523735 date "2009-09-28" @default.
- W2159523735 modified "2023-10-18" @default.
- W2159523735 title "Highly Efficient Asymmetric Synthesis of Vinylic Amino Alcohols by Zn-Promoted Benzoyloxyallylation of Chiral<i>N</i>-<i>tert</i>-Butanesulfinyl Imines: Facile and Rapid Access to (−)-Cytoxazone" @default.
- W2159523735 cites W1583348233 @default.
- W2159523735 cites W1686366659 @default.
- W2159523735 cites W1965128725 @default.
- W2159523735 cites W1969823780 @default.
- W2159523735 cites W1972161284 @default.
- W2159523735 cites W1979277587 @default.
- W2159523735 cites W1980864184 @default.
- W2159523735 cites W1981087038 @default.
- W2159523735 cites W1982415720 @default.
- W2159523735 cites W1982450534 @default.
- W2159523735 cites W1990350767 @default.
- W2159523735 cites W1994837034 @default.
- W2159523735 cites W1996859169 @default.
- W2159523735 cites W2001912872 @default.
- W2159523735 cites W2002687282 @default.
- W2159523735 cites W2007933607 @default.
- W2159523735 cites W2008041726 @default.
- W2159523735 cites W2008468937 @default.
- W2159523735 cites W2016748169 @default.
- W2159523735 cites W2017596849 @default.
- W2159523735 cites W2018352361 @default.
- W2159523735 cites W2022797753 @default.
- W2159523735 cites W2024091686 @default.
- W2159523735 cites W2024444936 @default.
- W2159523735 cites W2028549079 @default.
- W2159523735 cites W2029034397 @default.
- W2159523735 cites W2029694100 @default.
- W2159523735 cites W2032051308 @default.
- W2159523735 cites W2034413227 @default.
- W2159523735 cites W2037520525 @default.
- W2159523735 cites W2037632901 @default.
- W2159523735 cites W2043327902 @default.
- W2159523735 cites W2045934848 @default.
- W2159523735 cites W2049055258 @default.
- W2159523735 cites W2057447362 @default.
- W2159523735 cites W2058060970 @default.
- W2159523735 cites W2064281493 @default.
- W2159523735 cites W2065689312 @default.
- W2159523735 cites W2072266835 @default.
- W2159523735 cites W2072486121 @default.
- W2159523735 cites W2077964655 @default.
- W2159523735 cites W2081870741 @default.
- W2159523735 cites W2087149174 @default.
- W2159523735 cites W2089713655 @default.
- W2159523735 cites W2090043830 @default.
- W2159523735 cites W2090098214 @default.
- W2159523735 cites W2091020460 @default.
- W2159523735 cites W2093809974 @default.
- W2159523735 cites W2095140954 @default.
- W2159523735 cites W2096660503 @default.
- W2159523735 cites W2131146694 @default.
- W2159523735 cites W2139304916 @default.
- W2159523735 cites W2141094368 @default.
- W2159523735 cites W2144625040 @default.
- W2159523735 cites W2151855986 @default.
- W2159523735 cites W2155670287 @default.
- W2159523735 cites W2156264089 @default.
- W2159523735 cites W2157604877 @default.
- W2159523735 cites W2158192184 @default.
- W2159523735 cites W2162354594 @default.
- W2159523735 cites W2164220459 @default.
- W2159523735 cites W2168679251 @default.
- W2159523735 cites W2171860535 @default.
- W2159523735 cites W2173156099 @default.
- W2159523735 cites W2175190153 @default.
- W2159523735 cites W2176340265 @default.
- W2159523735 cites W2417265524 @default.
- W2159523735 cites W2949115978 @default.
- W2159523735 cites W2949182968 @default.
- W2159523735 cites W2949220923 @default.
- W2159523735 cites W2949475498 @default.
- W2159523735 cites W2949921933 @default.
- W2159523735 cites W2950559915 @default.
- W2159523735 cites W2950672565 @default.
- W2159523735 cites W2951119851 @default.
- W2159523735 cites W2951279357 @default.
- W2159523735 cites W2951454188 @default.
- W2159523735 cites W2951608730 @default.
- W2159523735 cites W2951734601 @default.
- W2159523735 cites W2952026768 @default.
- W2159523735 cites W2952294553 @default.
- W2159523735 cites W2952299439 @default.
- W2159523735 cites W2952343702 @default.
- W2159523735 cites W2952350633 @default.
- W2159523735 cites W2952700005 @default.
- W2159523735 cites W2952741027 @default.
- W2159523735 cites W2952803606 @default.
- W2159523735 cites W2952846023 @default.
- W2159523735 cites W2953108113 @default.