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• W2159698549 abstract "Effets of pπpπ conjugation in phosphaalkenes have been considered by taking into account the results of X-ray structural studies and ab initio quantum-chemical calculations. The structural consequences of the conjugation depend to a certain extent on the character of the substituent and the place of its attachment to the double PC bond. Depending on the location of the substituent, bond polarization may strengthen or weaken (compensate for) the conjugation effects. A high contribution of the s-character of the lone electron pair of the P atom is an essential feature of the electron structure of a phosphaalkene." @default.
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• W2159698549 date "1991-04-01" @default.
• W2159698549 modified "2023-10-12" @default.
• W2159698549 title "Peculiarities ofp??p? conjugation in aminosubstituted phosphaalkenes" @default.
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• W2159698549 doi "https://doi.org/10.1002/hc.520020205" @default.
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