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- W2159809312 abstract "Cu(II)-based MOF (Cu-bipy-BTC, bipy=2,2′-bipyridine, BTC=1,3,5-tricarboxylate) was synthesized and immobilized on multiwalled carbon nanotubes. The prepared composite was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectra (XPS) and IR spectra. Then the material was modified onto the surface of a glassy carbon electrode, and showed a couple of well-defined redox peaks in a phosphate buffer solution (pH 6.0), ascribed to the redox process of CuII/I in the Cu-bipy-BTC. The modified electrode was then applied to fabricate a non-enzymatic hydrogen peroxide biosensor. The sensor showed good electrocatalytic activity toward the reduction of hydrogen peroxide with a wide linear range (3–70 µmol L−1 and 70–30000 µmol L−1) and a detection limit of 0.46 µmol L−1, as well as good stability and repeatability. In addition, the sensor has been successfully applied to determine hydrogen peroxide in water samples with good accuracy. Thus, the Cu-bipy-BTC/MWCNTs composite has great potential for applications in electrochemical sensors." @default.
- W2159809312 created "2016-06-24" @default.
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- W2159809312 date "2014-09-29" @default.
- W2159809312 modified "2023-10-15" @default.
- W2159809312 title "Cu(II)-Based MOF Immobilized on Multiwalled Carbon Nanotubes: Synthesis and Application for Nonenzymatic Detection of Hydrogen Peroxide with High Sensitivity" @default.
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- W2159809312 doi "https://doi.org/10.1002/elan.201400341" @default.
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