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- W2159905107 abstract "Abstract Two ruthenium hydride complexes commonly proposed as agents of unintended isomerization during olefin metathesis are examined for their activity in isomerization of estragole, a representative allylbenzene. Neither proves kinetically competent to account for the levels of isomerization observed during cross‐metathesis of estragole by the second‐generation Grubbs catalyst. A structure–activity analysis of selected ruthenium hydride complexes indicates that higher isomerization activity correlates with a more electrophilic metal center." @default.
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- W2159905107 date "2013-11-21" @default.
- W2159905107 modified "2023-10-18" @default.
- W2159905107 title "Isomerization During Olefin Metathesis: An Assessment of Potential Catalyst Culprits" @default.
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- W2159905107 doi "https://doi.org/10.1002/cctc.201300886" @default.
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