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• W2159968331 abstract "We report on a high energy resolution X-ray photoelectron spectroscopy plus supersonic molecular beam investigation of O/Ag(210). Two components are detected in the O1s spectra upon O2 adsorption, at binding energies EB =527.7 and 529.6 eV. The former peak persists up to 470 K, while the latter one decreases abruptly above 280 K. Comparison with a previous vibrational spectroscopy investigation on the same system (L. Vattuone, et al. Phys. Rev. Lett. 2003, 90, 228302) allows to assign both features to atomic oxygen. The low-energy peak is identified with adatoms, while the other is correlated to O atoms in subsurface sites. A minor contribution at the same binding energy, due to carbonates, is quantified by inspection of the C1s region and shows a different temperature behavior with respect to oxygen. Oxygen segregation into the subsurface region is observed when heating the crystal in the presence of supersurface oxygen." @default.
• W2159968331 created "2016-06-24" @default.
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• W2159968331 date "2005-12-18" @default.
• W2159968331 modified "2023-09-25" @default.
• W2159968331 title "Monitoring Super- and Subsurface Oxygen on Ag(210) by High Energy Resolution X-ray Photoelectron Spectroscopy: Subsurface Diffusion and Segregation" @default.
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• W2159968331 doi "https://doi.org/10.1021/jp0533168" @default.
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