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- W2160259511 abstract "Abstract Reported herein is the first purely chemical method for the dynamic kinetic resolution (DKR) of unprotected racemic α‐amino acids (α‐AAs), a method which can rival the economic efficiency of the enzymatic reactions. The DKR reaction principle can be readily applied for S/R interconversions of α‐AAs, the methodological versatility of which is unmatched by biocatalytic approaches. The presented process features a virtually complete stereochemical outcome, fully recyclable source of chirality, and operationally simple and convenient reaction conditions, thus allowing its ready scalability. A quite unique and novel mode of the thermodynamic control over the stereochemical outcome, including an exciting interplay between axial, helical, and central elements of chirality is proposed." @default.
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- W2160259511 date "2014-09-22" @default.
- W2160259511 modified "2023-10-18" @default.
- W2160259511 title "Chemical Dynamic Kinetic Resolution and<i>S</i>/<i>R</i> Interconversion of Unprotected α-Amino Acids" @default.
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- W2160259511 doi "https://doi.org/10.1002/anie.201407944" @default.
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