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- W2160443669 abstract "A novel high temperature cell capable of measuring electrochemical signals up to temperatures of 115 °C is reported. Characterisation of the cell has been undertaken by examining three differing systems. First the voltammetric response of a range of simple redox systems in both aqueous and non-aqueous media was recorded in order to deduce the activation energies for diffusion of these molecules. Next the steady state linear sweep voltammetric response of N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD) in dimethyl sulfoxide (DMSO) is assessed as a means of studying an inferred structural change of the solvent at elevated temperatures. A change in the activation energy for diffusion from 13 kJ mol−1 to 27 kJ mol−1 was observed as the temperature was raised. Finally, the electrochemically catalysed reaction of the radical cation TMPD+˙ with ascorbic acid is studied from 25 °C to 107 °C; the corresponding kinetic parameters are deduced." @default.
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- W2160443669 date "2003-01-01" @default.
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- W2160443669 title "Characterisation and application of a novel cell for mechanistic electrochemistry at elevated temperatures" @default.
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- W2160443669 doi "https://doi.org/10.1039/b307900g" @default.
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