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- W2160449751 abstract "Using all of the pertinent infrared solar spectra recorded at the Jungfraujoch Station, Switzerland, in 1951, 1975, and in 1984–1987, the increase of the vertical column abundance of methane, CH 4 , above that station has been reevaluated. The results are based on equivalent widths measurements of both the R 0 and the R 5 transitions of the 2 v 3 band of CH 4 at 6015.66 and 6067.09 cm −1 and on the CH 4 – v 3 band absorption characteristics between 2905.0 and 2908.8 cm −1 . The data between 1984 and 1987 provide a full seasonal cycle. They demonstrate a significant annual variation in the column abundance of CH 4 of ±10% around the mean. They also show variability on shorter time scales. The mean cumulative rate of increase of the total vertical column abundance of CH 4 above the Jungfraujoch is found to be (0.7 ± 0.1)% yr −1 between 1951 and 1986. Using a realistic CH 4 concentration profile throughout the troposphere and the stratosphere, we deduce volume mixing ratios at the altitude of the Jungfraujoch, equal to 1.28±0.08 and 1.64±0.09 ppm, for 1951 and for 1985–1987, respectively." @default.
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- W2160449751 date "1989-08-20" @default.
- W2160449751 modified "2023-09-26" @default.
- W2160449751 title "Secular increase of the vertical column abundance of methane derived from IR solar spectra recorded at the Jungfraujoch station" @default.
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- W2160449751 doi "https://doi.org/10.1029/jd094id08p11029" @default.
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