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• W2160459712 abstract "In seven steps: The antibiotic (+)-thiolactomycin was synthesized in seven steps and with 16 % overall yield from 4-acetoxy-2-methyl-2-buten-1-al, an intermediate of the industrial synthesis of vitamin A. Key transformations were the catalytic asymmetric Sharpless epoxidation of an ethoxycarbonyl-substituted pentadienol (93 % ee) and a regio- and stereoselective thiolysis of the resulting epoxide (see scheme)." @default.
• W2160459712 created "2016-06-24" @default.
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• W2160459712 date "2007-01-29" @default.
• W2160459712 modified "2023-10-17" @default.
• W2160459712 title "Variable Synthesis of the Optically Active Thiotetronic Acid Antibiotics Thiolactomycin, Thiotetromycin, and 834-B1" @default.
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• W2160459712 doi "https://doi.org/10.1002/anie.200603562" @default.
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