FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2160625523> ?p ?o ?g. }

• W2160625523 endingPage "1372" @default.
• W2160625523 startingPage "1363" @default.
• W2160625523 abstract "The application of supercritical fluid chromatography (SFC) to the enantiomeric separation of several chiral sulfoxides belonging to the family of the substituted benzimidazoles, including omeprazole, lansoprazole, pantoprazole, rabeprazole, oxfendazole and ricobendazole, is presented in this work. The column employed was Chiralpak AD and the effect of different chromatographic conditions was studied. The results obtained showed that all the compounds can be enantiomerically resolved using SFC, with resolutions higher than 2 and analysis times that in most cases were lower than 10 min. Alcohol type modifiers provided the best results, with ricobendazole, oxfendazole, and omeprazole showing the highest retentions and resolutions. Study of the temperature effect revealed that, in general, the isoelution temperature was above the temperatures assayed, except in the cases of omeprazole, lansoprazole, and oxfendazole with ethanol as modifier and pantoprazole with acetonitrile. Enthalpy-entropy compensation could also be demonstrated for the retention of the first and second eluted enantiomers as well as for the selectivity, with compensation temperatures of 25 degrees C, 45 degrees C, and 83 degrees C, respectively. Reversal of elution on change of the organic modifier was only observed for omeprazole using 2-propanol." @default.
• W2160625523 created "2016-06-24" @default.
• W2160625523 creator A5022275878 @default.
• W2160625523 creator A5041657846 @default.
• W2160625523 creator A5079688872 @default.
• W2160625523 creator A5089771714 @default.
• W2160625523 creator A5090181869 @default.
• W2160625523 date "2006-07-01" @default.
• W2160625523 modified "2023-10-10" @default.
• W2160625523 title "Enantiomeric separation of chiral sulfoxides by supercritical fluid chromatography" @default.
• W2160625523 cites W139217710 @default.
• W2160625523 cites W1964672927 @default.
• W2160625523 cites W1965612292 @default.
• W2160625523 cites W1969589235 @default.
• W2160625523 cites W1972364978 @default.
• W2160625523 cites W1980848365 @default.
• W2160625523 cites W1991238236 @default.
• W2160625523 cites W1991998089 @default.
• W2160625523 cites W1992911862 @default.
• W2160625523 cites W1993990817 @default.
• W2160625523 cites W2006585685 @default.
• W2160625523 cites W2009012888 @default.
• W2160625523 cites W2011945744 @default.
• W2160625523 cites W2018272856 @default.
• W2160625523 cites W2021560264 @default.
• W2160625523 cites W2028019864 @default.
• W2160625523 cites W2029034260 @default.
• W2160625523 cites W2046109662 @default.
• W2160625523 cites W2052097369 @default.
• W2160625523 cites W2054671518 @default.
• W2160625523 cites W2054680364 @default.
• W2160625523 cites W2056659360 @default.
• W2160625523 cites W2061416369 @default.
• W2160625523 cites W2066263508 @default.
• W2160625523 cites W2069276755 @default.
• W2160625523 cites W2087963657 @default.
• W2160625523 cites W2093638454 @default.
• W2160625523 cites W2119797921 @default.
• W2160625523 cites W2135335180 @default.
• W2160625523 cites W2169813773 @default.
• W2160625523 doi "https://doi.org/10.1002/jssc.200600009" @default.
• W2160625523 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16894780" @default.
• W2160625523 hasPublicationYear "2006" @default.
• W2160625523 type Work @default.
• W2160625523 sameAs 2160625523 @default.
• W2160625523 citedByCount "40" @default.
• W2160625523 countsByYear W21606255232012 @default.
• W2160625523 countsByYear W21606255232013 @default.
• W2160625523 countsByYear W21606255232014 @default.
• W2160625523 countsByYear W21606255232015 @default.
• W2160625523 countsByYear W21606255232016 @default.
• W2160625523 countsByYear W21606255232017 @default.
• W2160625523 countsByYear W21606255232018 @default.
• W2160625523 countsByYear W21606255232019 @default.
• W2160625523 countsByYear W21606255232021 @default.
• W2160625523 countsByYear W21606255232022 @default.
• W2160625523 crossrefType "journal-article" @default.
• W2160625523 hasAuthorship W2160625523A5022275878 @default.
• W2160625523 hasAuthorship W2160625523A5041657846 @default.
• W2160625523 hasAuthorship W2160625523A5079688872 @default.
• W2160625523 hasAuthorship W2160625523A5089771714 @default.
• W2160625523 hasAuthorship W2160625523A5090181869 @default.
• W2160625523 hasConcept C121332964 @default.
• W2160625523 hasConcept C126322002 @default.
• W2160625523 hasConcept C178790620 @default.
• W2160625523 hasConcept C179998833 @default.
• W2160625523 hasConcept C185592680 @default.
• W2160625523 hasConcept C203147553 @default.
• W2160625523 hasConcept C2777463227 @default.
• W2160625523 hasConcept C2777498785 @default.
• W2160625523 hasConcept C2778715759 @default.
• W2160625523 hasConcept C2781315423 @default.
• W2160625523 hasConcept C3288061 @default.
• W2160625523 hasConcept C43617362 @default.
• W2160625523 hasConcept C486523 @default.
• W2160625523 hasConcept C62520636 @default.
• W2160625523 hasConcept C71924100 @default.
• W2160625523 hasConcept C73826308 @default.
• W2160625523 hasConceptScore W2160625523C121332964 @default.
• W2160625523 hasConceptScore W2160625523C126322002 @default.
• W2160625523 hasConceptScore W2160625523C178790620 @default.
• W2160625523 hasConceptScore W2160625523C179998833 @default.
• W2160625523 hasConceptScore W2160625523C185592680 @default.
• W2160625523 hasConceptScore W2160625523C203147553 @default.
• W2160625523 hasConceptScore W2160625523C2777463227 @default.
• W2160625523 hasConceptScore W2160625523C2777498785 @default.
• W2160625523 hasConceptScore W2160625523C2778715759 @default.
• W2160625523 hasConceptScore W2160625523C2781315423 @default.
• W2160625523 hasConceptScore W2160625523C3288061 @default.
• W2160625523 hasConceptScore W2160625523C43617362 @default.
• W2160625523 hasConceptScore W2160625523C486523 @default.
• W2160625523 hasConceptScore W2160625523C62520636 @default.
• W2160625523 hasConceptScore W2160625523C71924100 @default.
• W2160625523 hasConceptScore W2160625523C73826308 @default.
• W2160625523 hasIssue "10" @default.
• W2160625523 hasLocation W21606255231 @default.
• W2160625523 hasLocation W21606255232 @default.
• W2160625523 hasOpenAccess W2160625523 @default.

• next