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- W2160636699 abstract "The cluster [Fe2S2(SBut)4]2− on reacting with L-cysteine ethyl ester hydrochloride (HCys-OEt · HCl) converts to the tetranuclear cysteinate-bound cluster [Fe4S4(Cys-OEt · HCl)4]2−. In contrast, the dinuclear tyrosinate-bound cluster [Fe2S2(Tyr-OMe)4]2− (HTyr-OMe = L-tyrosine methyl ester) can be prepared from either [Fe2S2(SBut)4]2−, or as a decomposition product in the reaction of hexanuclear [Fe6S6Cl6]3− with NaTyr-OMe. Under appropriate conditions the hexanuclear tyrosinate-bound cluster [Fe6S6(Tyr-OMe)6]3− can be isolated. The thermal stability of clusters [Fe6S6(XR)6]3− (X=S, O) toward conversion to tetranuclear [Fe4S4(XR)4]2− lies in the order tyrosinate-≥phenolate->thiophenolate-bound cluster. 1H NMR and Mössbauer spectroscopies are used to unequivocally identify the products." @default.
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- W2160636699 date "1996-06-01" @default.
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- W2160636699 title "Amino acid induced iron-sulfur cluster interconversions studied by 1H NMR and Mössbauer spectroscopies" @default.
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- W2160636699 doi "https://doi.org/10.1016/0020-1693(95)04953-3" @default.
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