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- W2160677485 abstract "Mix and match: Topotactic hydride reduction allows the first synthesis of the fully reduced parent phase, Sr4Fe6O12, of the important family Sr4Fe6O13±δ. The structure provides a rare example of pairs of edge-linked tetrahedra, in this case containing a random arrangement of FeII and FeIII centers at 300 K. On cooling, charge order occurs so that each pair of tetrahedra has one FeII (white) and one FeIII (black) center. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2160677485 date "2013-03-26" @default.
- W2160677485 modified "2023-09-25" @default.
- W2160677485 title "Sr4Fe6O12: Low-Temperature Fe2+-Fe3+Charge Order within Pairs of Edge-Linked Tetrahedra" @default.
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- W2160677485 doi "https://doi.org/10.1002/anie.201209473" @default.
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