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- W2160691796 abstract "Values for the rate constants of the catalytic step HLAD-NADH + ketone → HLAD-NAD+ alcohol in the HLAD catalyzed reduction of some 2-alkyl cyclohexanones, geminal dimethyl cyclohexanones, cycloalkanones and bicyclic ketones are presented. Also the thermodynamic parameters of activation are given and they are compared with the activation parameters of the NaBH4 reduction leading to a better understanding of some forces at work in enzymatic catalysis. The results are rationalized in the same way as was previously done for the 3-alkyl and 4-alkyl cyclohexanones. A reaction model is obtained in which steric hindrances and hydrophobic zones are responsible for rate decreasing, respectively increasing interactions between enzyme and substrates." @default.
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- W2160691796 date "2010-09-01" @default.
- W2160691796 modified "2023-09-24" @default.
- W2160691796 title "Enzymatic “In Vitro” Reduction of Ketones VII.(1) Reduction rates and stereochemistry of the HLAD catalyzed reduction of 2-alkyl cyclohexanones, dimethyl cyclohexanones, cycloalkanones and bicycloalkanones" @default.
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- W2160691796 doi "https://doi.org/10.1002/bscb.19800890510" @default.
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