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• W2160706091 startingPage "1657" @default.
• W2160706091 abstract "Abstract The correlation equation log k 25 °C = s f ( N f + E f ), where s f and N f are nucleofuge‐specific parameters referring to leaving group/solvent combinations and E f are electrofuge‐specific parameters referring to the incipient carbocation R + , are used to predict ionization rate constants of alkyl derivatives RX. We show how to employ the E f parameters of reference electrofuges and the s f and N f parameters of reference nucleofuges reported in the preceding article for determining further s f , N f , and E f parameters. Since s f is usually close to 1.0, one comes to the semiquantitative rule that at 25 °C, compounds RX for which N f + E f >−2 will solvolyze with half‐lives of less than a minute, while the solvolysis half‐lives will exceed 1 month if N f + E f <−6.5." @default.
• W2160706091 created "2016-06-24" @default.
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• W2160706091 date "2006-02-01" @default.
• W2160706091 modified "2023-10-17" @default.
• W2160706091 title "How Fast Do RX Bonds Ionize? A Semiquantitative Approach" @default.
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• W2160706091 doi "https://doi.org/10.1002/chem.200500847" @default.
• W2160706091 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16331713" @default.
• W2160706091 hasPublicationYear "2006" @default.
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