Matches in SemOpenAlex for { <https://semopenalex.org/work/W2160777382> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W2160777382 endingPage "2029" @default.
- W2160777382 startingPage "2022" @default.
- W2160777382 abstract "The spectrum of pulse-irradiated liquid 3-methyloctane at 127 K has maxima around 625 and 2100 nm. The latter is well-known as being due to the solvated electron (e s − ). The former is attributed to a positive ion because it is eliminated by the addition of triethylamine, but remains in solutions of electron scavengers, and is very similar to bands observed earlier by Louwrier and Hamill in glassy solutions at 77 K of higher hydrocarbons in CCl 4 or CO 2 -bubbled 3-methylpentane. At temperatures of 127 K and less the initial decay rate of e s − is greatly decreased by the addition of ∼6mol% triethylamine. The result is interpreted as indicating that at low temperatures the mobility of the initial hydrocarbon positive ion is much greater than that of either e s − or the positive ion in triethylamine solutions, and therefore the initial hydrocarbon positive ion must be the parent radical cation which moves by resonance charge transfer. As the temperature of pure 3-methyloctane is raised from 103 to 153 K, the initial Gε 650 decreases by about 30% while initial Gε 2100 almost doubles; because of these and other observations it is tentatively suggested that a second solvated electron is also produced." @default.
- W2160777382 created "2016-06-24" @default.
- W2160777382 creator A5040720524 @default.
- W2160777382 creator A5048530810 @default.
- W2160777382 creator A5086719622 @default.
- W2160777382 date "1977-06-01" @default.
- W2160777382 modified "2023-09-24" @default.
- W2160777382 title "Optical study of electrons and positive ions in pulse-irradiated liquid 3-methyloctane at low temperatures" @default.
- W2160777382 doi "https://doi.org/10.1139/v77-283" @default.
- W2160777382 hasPublicationYear "1977" @default.
- W2160777382 type Work @default.
- W2160777382 sameAs 2160777382 @default.
- W2160777382 citedByCount "28" @default.
- W2160777382 crossrefType "journal-article" @default.
- W2160777382 hasAuthorship W2160777382A5040720524 @default.
- W2160777382 hasAuthorship W2160777382A5048530810 @default.
- W2160777382 hasAuthorship W2160777382A5086719622 @default.
- W2160777382 hasBestOaLocation W21607773821 @default.
- W2160777382 hasConcept C111337013 @default.
- W2160777382 hasConcept C113196181 @default.
- W2160777382 hasConcept C121332964 @default.
- W2160777382 hasConcept C139066938 @default.
- W2160777382 hasConcept C145148216 @default.
- W2160777382 hasConcept C147120987 @default.
- W2160777382 hasConcept C178790620 @default.
- W2160777382 hasConcept C185544564 @default.
- W2160777382 hasConcept C185592680 @default.
- W2160777382 hasConcept C2777207669 @default.
- W2160777382 hasConcept C2781283055 @default.
- W2160777382 hasConcept C42296456 @default.
- W2160777382 hasConcept C62520636 @default.
- W2160777382 hasConcept C66887884 @default.
- W2160777382 hasConcept C75473681 @default.
- W2160777382 hasConceptScore W2160777382C111337013 @default.
- W2160777382 hasConceptScore W2160777382C113196181 @default.
- W2160777382 hasConceptScore W2160777382C121332964 @default.
- W2160777382 hasConceptScore W2160777382C139066938 @default.
- W2160777382 hasConceptScore W2160777382C145148216 @default.
- W2160777382 hasConceptScore W2160777382C147120987 @default.
- W2160777382 hasConceptScore W2160777382C178790620 @default.
- W2160777382 hasConceptScore W2160777382C185544564 @default.
- W2160777382 hasConceptScore W2160777382C185592680 @default.
- W2160777382 hasConceptScore W2160777382C2777207669 @default.
- W2160777382 hasConceptScore W2160777382C2781283055 @default.
- W2160777382 hasConceptScore W2160777382C42296456 @default.
- W2160777382 hasConceptScore W2160777382C62520636 @default.
- W2160777382 hasConceptScore W2160777382C66887884 @default.
- W2160777382 hasConceptScore W2160777382C75473681 @default.
- W2160777382 hasIssue "11" @default.
- W2160777382 hasLocation W21607773821 @default.
- W2160777382 hasOpenAccess W2160777382 @default.
- W2160777382 hasPrimaryLocation W21607773821 @default.
- W2160777382 hasRelatedWork W130229104 @default.
- W2160777382 hasRelatedWork W1974055849 @default.
- W2160777382 hasRelatedWork W1974416061 @default.
- W2160777382 hasRelatedWork W1994502076 @default.
- W2160777382 hasRelatedWork W2025066554 @default.
- W2160777382 hasRelatedWork W2025558374 @default.
- W2160777382 hasRelatedWork W2045899686 @default.
- W2160777382 hasRelatedWork W2058986864 @default.
- W2160777382 hasRelatedWork W2062163549 @default.
- W2160777382 hasRelatedWork W223580090 @default.
- W2160777382 hasVolume "55" @default.
- W2160777382 isParatext "false" @default.
- W2160777382 isRetracted "false" @default.
- W2160777382 magId "2160777382" @default.
- W2160777382 workType "article" @default.