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- W2160917692 abstract "In this paper, we show a common strategy to synthesize tetraalkenylmethanes, a cross-linker series for building three-dimensional hydrocarbon networks. To demonstrate the feasibility of this method, we have synthesized tetrapentenylmethane. Attempts to synthesize this cross-linker from pentaerythrityl tetrabromide using substitution reactions resulted in the formation of a spiro compound due to intramolecular cyclization. We also show that the difficulty in reactions at the neopentyl carbon site is due to the neopentyl carbanion stability, not the sterics." @default.
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- W2160917692 date "2011-12-01" @default.
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- W2160917692 title "Synthesis of Tetraalkenylmethane: Building Blocks for Three-Dimensional Hydrocarbon Networks" @default.
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- W2160917692 doi "https://doi.org/10.1080/10601325.2011.620416" @default.
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