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- W2160992992 abstract "The synthesis and the solution behavior of rigid, rodlike cationic polyelectrolytes having (i) poly(p-phenylene) backbones and (ii) main chains composed of 4,4“-bis(2,2′:6′,2”-terpyridine)2′,5′-dihexyl-p-terphenyl moieties and ruthenium(II) centers are presented. All these polymers are shown to have a homogeneous constitution and degrees of polymerization of up to Pn ≈ 70. Their solution properties were analyzed using viscosimetry, small-angle X-ray scattering (SAXS) and osmometry. Pronounced polyelectrolyte effects were found in salt-free solutions using viscosimetry. Small-angle X-ray scattering demonstrated directly the strong correlation of the counterions and the macroions. The osmotic coefficients measured in salt-free solution as function of polyelectrolyte concentration were found to be lower than predicted by the cell model." @default.
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- W2160992992 date "1999-08-01" @default.
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- W2160992992 title "Synthesis and solution properties of rodlike polyelectrolytes" @default.
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- W2160992992 doi "https://doi.org/10.1002/masy.19991420107" @default.
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