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- W2161147173 endingPage "2026" @default.
- W2161147173 startingPage "2015" @default.
- W2161147173 abstract "Abstract Molecular organization behavior and visible light absorption ability are important factors for organic materials to be used in efficient bulk heterojunction solar cells applications. In this context, a series of monosubstituted fluorenyl hexa‐ peri ‐hexabenzocoronene (FHBC) are synthesized with the aim to combine the self‐association property of the FHBC unit with broadened light absorption of a small molecule organic dye, bisthienylbenzothiadiazole (TBT). Optical and electrochemical properties of the FHBC compounds vary according to their structures. Introduction of a TBT unit into the FHBC system broadens the absorption. All of the FHBC compounds show strong π – π intermolecular association in solution. X‐ray scattering measurements on thermally extruded filaments and thin films showed ordered alignment of these compounds in the solid state. In atomic force microscopy experiments, nanoscale phase separation is observed in thin films of FHBC and fullerene derivative blends. Solar cell devices with these compounds as donors are fabricated. FHBC compounds with the TBT unit show higher short circuit current while the high open circuit voltages are maintained. With C 60 derivative as acceptor, power conversion efficiency of 1.12% is achieved in the unoptimized solar cell devices under simulated solar irradiation. The efficiency was further improved to 1.64% when C 70 derivative was used as the acceptor." @default.
- W2161147173 created "2016-06-24" @default.
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- W2161147173 date "2012-03-16" @default.
- W2161147173 modified "2023-10-17" @default.
- W2161147173 title "Solution Processable Monosubstituted Hexa-Peri-Hexabenzocoronene Self-Assembling Dyes" @default.
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- W2161147173 doi "https://doi.org/10.1002/adfm.201102141" @default.
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